Crystal structure of the cysteine-rich domain of mannose receptor complexed with a sulfated carbohydrate ligand

J Exp Med. 2000 Apr 3;191(7):1105-16. doi: 10.1084/jem.191.7.1105.

Abstract

The macrophage and epithelial cell mannose receptor (MR) binds carbohydrates on foreign and host molecules. Two portions of MR recognize carbohydrates: tandemly arranged C-type lectin domains facilitate carbohydrate-dependent macrophage uptake of infectious organisms, and the NH(2)-terminal cysteine-rich domain (Cys-MR) binds to sulfated glycoproteins including pituitary hormones. To elucidate the mechanism of sulfated carbohydrate recognition, we determined crystal structures of Cys-MR alone and complexed with 4-sulfated-N-acetylgalactosamine at 1.7 and 2.2 A resolution, respectively. Cys-MR folds into an approximately three-fold symmetric beta-trefoil shape resembling fibroblast growth factor. The sulfate portions of 4-sulfated-N-acetylgalactosamine and an unidentified ligand found in the native crystals bind in a neutral pocket in the third lobe. We use the structures to rationalize the carbohydrate binding specificities of Cys-MR and compare the recognition properties of Cys-MR with other beta-trefoil proteins.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, P.H.S.

MeSH terms

  • Acetylgalactosamine / analogs & derivatives*
  • Acetylgalactosamine / chemistry
  • Acetylgalactosamine / metabolism
  • Amino Acid Sequence
  • Animals
  • Carbohydrate Conformation*
  • Carbohydrate Metabolism
  • Carbohydrates / chemistry*
  • Cell Line, Transformed
  • Crystallography, X-Ray
  • Cysteine*
  • Humans
  • Lectins, C-Type*
  • Ligands
  • Mannose Receptor
  • Mannose-Binding Lectins*
  • Mice
  • Molecular Sequence Data
  • Protein Conformation*
  • Receptors, Cell Surface / chemistry*
  • Receptors, Cell Surface / metabolism
  • Recombinant Fusion Proteins / chemistry
  • Recombinant Fusion Proteins / metabolism

Substances

  • Carbohydrates
  • Lectins, C-Type
  • Ligands
  • Mannose Receptor
  • Mannose-Binding Lectins
  • Receptors, Cell Surface
  • Recombinant Fusion Proteins
  • N-acetylgalactosamine 4-sulfate
  • Cysteine
  • Acetylgalactosamine