Specificity and mechanism analysis of hepatitis C virus RNA-dependent RNA polymerase

Arch Biochem Biophys. 2000 May 1;377(1):129-34. doi: 10.1006/abbi.2000.1749.

Abstract

The RNA-dependent RNA polymerase encoded by the hepatitis C virus (HCV) NS5B gene has been expressed as a nonfusion protein in bacterial cells and purified to homogeneity using sequential chromatographic columns. The purified NS5B protein exhibited RNA-dependent RNA polymerase activity using poly(A) template and the K(m) and V(max) were determined as 8.4 microM and 1976 pmol/mg-min, respectively. This full-length NS5B protein exhibited much stronger binding affinity toward the 30-mer poly(G) than other homopolymeric RNAs of the same size. For the first time, we demonstrate that the HCV NS5B was able to bind various ribonucleotides. Using a panel of oligonucleotides varying in length, we studied the NS5B catalytic efficiency and proposed the size of the NS5B active site to be 8-10 nucleotides. The multifunctional nature of NS5B protein is also discussed and compared with other viral RNA polymerases.

MeSH terms

  • Binding Sites
  • Catalysis / drug effects
  • Cations, Divalent / pharmacology
  • Dose-Response Relationship, Drug
  • Escherichia coli / genetics
  • Hepacivirus / enzymology*
  • Hepacivirus / genetics
  • Kinetics
  • Poly A / genetics
  • Poly A / metabolism
  • Poly G / genetics
  • Poly G / metabolism
  • Protein Binding
  • RNA / genetics
  • RNA, Viral / biosynthesis
  • RNA, Viral / genetics
  • RNA-Dependent RNA Polymerase / isolation & purification
  • RNA-Dependent RNA Polymerase / metabolism*
  • Recombinant Proteins / isolation & purification
  • Recombinant Proteins / metabolism
  • Ribonucleotides / genetics
  • Ribonucleotides / metabolism
  • Substrate Specificity
  • Templates, Genetic
  • Thermodynamics

Substances

  • Cations, Divalent
  • RNA primers
  • RNA, Viral
  • Recombinant Proteins
  • Ribonucleotides
  • Poly A
  • Poly G
  • RNA
  • RNA-Dependent RNA Polymerase