The masses of 31 neutron-rich nuclei in the range A = 29-47 have been measured. The precision of 19 masses has been significantly improved and 12 masses were measured for the first time. The neutron-rich Cl, S, and P isotopes are seen to exhibit a change in shell structure around N = 28. Comparison with shell model and relativistic mean field calculations demonstrate that the observed effects arise from deformed prolate ground state configurations associated with shape coexistence. Evidence for shape coexistence is provided by the observation of an isomer in 43S.