7,8-Diphenyl-9-dimethylsulfido-10,11-mu-hydro-7, 8-dicarba-nido-undecaborane(9)

Acta Crystallogr C. 2000 Nov:56 Pt 11:1399-400. doi: 10.1107/s0108270100011471.

Abstract

In the title compound, C(16)H(25)B(9)S, there are two crystallographically independent molecules, and the conformations of the phenyl and SMe(2) substituents indicate some intramolecular steric crowding. The bridging H atom is asymmetrically disposed. The title compound is a precursor to a crowded vertex-labelled nido carborane ligand important in establishing the mechanism of isomerization of icosahedral heteroboranes.