Dissection of the functional and structural domains of phosphorelay histidine kinase A of Bacillus subtilis

J Bacteriol. 2001 May;183(9):2795-802. doi: 10.1128/JB.183.9.2795-2802.2001.

Abstract

The initiation of sporulation in Bacillus subtilis results primarily from phosphoryl group input into the phosphorelay by histidine kinases, the major kinase being kinase A. Kinase A is active as a homodimer, the protomer of which consists of an approximately 400-amino-acid N-terminal putative signal-sensing region and a 200-amino-acid C-terminal autokinase. On the basis of sequence similarity, the N-terminal region may be subdivided into three PAS domains: A, B, and C, located from the N- to the C-terminal end. Proteolysis experiments and two-hybrid analyses indicated that dimerization of the N-terminal region is accomplished through the PAS-B/PAS-C region of the molecule, whereas the most amino-proximal PAS-A domain is not dimerized. N-terminal deletions generated with maltose binding fusion proteins showed that an intact PAS-A domain is very important for enzymatic activity. Amino acid substitution mutations in PAS-A as well as PAS-C affected the in vivo activity of kinase A, suggesting that both PAS domains are required for signal sensing. The C-terminal autokinase, when produced without the N-terminal region, was a dimer, probably because of the dimerization required for formation of the four-helix-bundle phosphotransferase domain. The truncated autokinase was virtually inactive in autophosphorylation with ATP, whereas phosphorylation of the histidine of the phosphotransfer domain by back reactions from Spo0F~P appeared normal. The phosphorylated autokinase lost the ability to transfer its phosphoryl group to ADP, however. The N-terminal region appears to be essential both for signal sensing and for maintaining the correct conformation of the autokinase component domains.

Publication types

  • Research Support, U.S. Gov't, P.H.S.

MeSH terms

  • Adenosine Triphosphate / metabolism
  • Amino Acid Substitution
  • Bacillus subtilis / enzymology*
  • Bacterial Proteins / chemistry*
  • Bacterial Proteins / genetics
  • Carrier Proteins / genetics
  • Catalytic Domain
  • Gene Deletion
  • Histidine / metabolism
  • Histidine Kinase
  • Maltose-Binding Proteins
  • Molecular Weight
  • Mutation
  • Phosphorylation
  • Protein Kinases / chemistry*
  • Protein Kinases / genetics
  • Protein Kinases / metabolism
  • Protein Structure, Secondary
  • Signal Transduction
  • Spores, Bacterial / enzymology

Substances

  • Bacterial Proteins
  • Carrier Proteins
  • Maltose-Binding Proteins
  • kinA protein, Bacillus subtilis
  • Histidine
  • Adenosine Triphosphate
  • Protein Kinases
  • Histidine Kinase