Three new azaanthracene alkaloids, 6,7-dimethoxycleistopholine (3), 5-hydroxy-6-methoxycleistopholine (4), and 5-hydroxy-6,7-dimethoxycleistopholine (5), along with 14 known alkaloids, including the new natural product 6-methoxycleistopholine (2), were isolated from a CH2Cl2 extract of the branches of Porcelia macrocarpa.