Abstract
The potency and selectivity of a series of 5-hetero-2-iminohexahydroazepines were examined as inhibitors of the three human NOS isoforms. The effect of ring substitution of the 5-carbon for a heteroatom is presented. Potencies (IC(50)'s) for these inhibitors are in the low micromolar range for hi-NOS with some examples exhibiting a 500x selectivity versus hec-NOS.
MeSH terms
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Azepines / chemical synthesis
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Azepines / chemistry
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Azepines / pharmacology*
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Enzyme Inhibitors / chemical synthesis
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Enzyme Inhibitors / chemistry
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Enzyme Inhibitors / pharmacology*
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Humans
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Inhibitory Concentration 50
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Isoenzymes / antagonists & inhibitors*
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Nitric Oxide Synthase / antagonists & inhibitors*
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Nitric Oxide Synthase Type II
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Structure-Activity Relationship
Substances
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Azepines
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Enzyme Inhibitors
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Isoenzymes
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NOS2 protein, human
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Nitric Oxide Synthase
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Nitric Oxide Synthase Type II