New microporous coordination polymer affording guest-coordination sites at channel walls

Shin-ichiro Noro; Susumu Kitagawa; Masahiro Yamashita; Tatsuo Wada

doi:10.1039/b108695b

New microporous coordination polymer affording guest-coordination sites at channel walls

Chem Commun (Camb). 2002 Feb 7:(3):222-3. doi: 10.1039/b108695b.

Authors

Shin-ichiro Noro¹, Susumu Kitagawa, Masahiro Yamashita, Tatsuo Wada

Affiliation

¹ Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan.

PMID: 12132482
DOI: 10.1039/b108695b

Abstract

Utilization of a metalloligand, ([Cu(2,4-pydca)2(H2O)].2Et3NH) (1) (2,4-pydca = pyridine-2,4-dicarboxylate), as a building unit provides a novel porous coordination polymer, ([ZnCu(2,4-pydca)2(H2O)3(DMF)].DMF)n (2), in which the Zn(II) ion at the node of the network acts as a linker and the Cu(II) ion in the channel wall is available for guest-coordination.