Fluorescence resonance energy transfer to probe human M1 muscarinic receptor structure and drug binding properties

J Neurochem. 2003 May;85(3):768-78. doi: 10.1046/j.1471-4159.2003.01717.x.

Abstract

Human M1 muscarinic receptor chimeras were designed (i) to allow detection of their interaction with the fluorescent antagonist pirenzepine labelled with Bodipy [558/568], through fluorescence resonance energy transfer, (ii) to investigate the structure of the N-terminal extracellular moiety of the receptor and (iii) to set up a fluorescence-based assay to identify new muscarinic ligands. Enhanced green (or yellow) fluorescent protein (EGFP or EYFP) was fused, through a linker, to a receptor N-terminus of variable length so that the GFP barrel was separated from the receptor first transmembrane domain by six to 33 amino-acids. Five fluorescent constructs exhibit high expression levels as well as pharmacological and functional properties superimposable on those of the native receptor. Bodipy-pirenzepine binds to the chimeras with similar kinetics and affinities, indicating a similar mode of interaction of the ligand with all of them. From the variation in energy transfer efficiencies determined for four different receptor-ligand complexes, relative donor (EGFP)-acceptor (Bodipy) distances were estimated. They suggest a compact architecture for the muscarinic M1 receptor amino-terminal domain which may fold in a manner similar to that of rhodopsin. Finally, this fluorescence-based assay, prone to miniaturization, allows reliable detection of unlabelled competitors.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amino Acid Sequence
  • Binding, Competitive / physiology
  • Cell Line
  • Fluorescence Resonance Energy Transfer
  • Fluorescent Dyes
  • Humans
  • Kidney / cytology
  • Kidney / metabolism
  • Ligands
  • Luminescent Proteins / genetics
  • Molecular Sequence Data
  • Receptor, Muscarinic M1
  • Receptors, Muscarinic / chemistry*
  • Receptors, Muscarinic / genetics
  • Receptors, Muscarinic / metabolism*
  • Recombinant Fusion Proteins / chemistry
  • Recombinant Fusion Proteins / genetics
  • Recombinant Fusion Proteins / metabolism
  • Sensitivity and Specificity
  • Transfection

Substances

  • Fluorescent Dyes
  • Ligands
  • Luminescent Proteins
  • Receptor, Muscarinic M1
  • Receptors, Muscarinic
  • Recombinant Fusion Proteins