Discovery and characterization of cooperative ligand binding in the adaptive region of interleukin-2

Biochemistry. 2003 Jun 3;42(21):6475-83. doi: 10.1021/bi034138g.

Abstract

The cytokine hormone interleukin-2 (IL-2) contains a highly adaptive region that binds small, druglike molecules. The binding properties of this adaptive region have been explored using a "tethering" method that relies on the formation of a disulfide bond between the protein and small-molecule ligands. Using tethering, surface plasmon resonance (SPR), and X-ray crystallography, we have discovered that the IL-2 adaptive region contains at least two cooperative binding sites where the binding of a first ligand to one site promotes or antagonizes the binding of a second ligand to the second site. Cooperative energies of interaction of -2 kcal/mol are observed. The observation that the adaptive region contains two adjacent sites may lead to the development of tight-binding antagonists of a protein-protein interaction. Cooperative ligand binding in the adaptive region of IL-2 underscores the importance of protein dynamics in molecular recognition. The tethering approach provides a novel and general strategy for discovering such cooperative binding interactions in specific, flexible regions of protein structure.

MeSH terms

  • Binding Sites
  • Binding, Competitive
  • Biochemistry / methods
  • Crystallography, X-Ray
  • Cysteine / chemistry
  • Disulfides / chemistry
  • Dose-Response Relationship, Drug
  • Humans
  • Interleukin-2 / chemistry*
  • Interleukin-2 / metabolism
  • Ligands
  • Mass Spectrometry
  • Models, Biological
  • Models, Chemical
  • Models, Molecular
  • Protein Binding
  • Surface Plasmon Resonance
  • Thermodynamics
  • Time Factors

Substances

  • Disulfides
  • Interleukin-2
  • Ligands
  • Cysteine

Associated data

  • PDB/1M47
  • PDB/1M48
  • PDB/1M4A
  • PDB/1M4B
  • PDB/1M4C