A novel bilayer cobalt(II)-organic framework with nanoscale channels accommodating large organic molecules

Junhua Luo; Maochun Hong; Ruihu Wang; Rong Cao; Lei Han; Daqiang Yuan; Zhenzhong Lin; Youfu Zhou

doi:10.1021/ic034064x

A novel bilayer cobalt(II)-organic framework with nanoscale channels accommodating large organic molecules

Inorg Chem. 2003 Jul 28;42(15):4486-8. doi: 10.1021/ic034064x.

Authors

Junhua Luo¹, Maochun Hong, Ruihu Wang, Rong Cao, Lei Han, Daqiang Yuan, Zhenzhong Lin, Youfu Zhou

Affiliation

¹ State Key Laboratory of Structural Chemistry, Fujian Institute of the Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China.

PMID: 12870928
DOI: 10.1021/ic034064x

Abstract

A unique noninterpenetrated 2D bilayer cobalt(II)-organic framework, [[Co(dpe)(NO(2)-BDC)].0.5(dpe)](n).nH(2)O (1), possessing nanoscale rectangular channels that clathrate large organic molecules, has been hydrothermally synthesized by reaction of cobalt(II) salt with 5-nitro-1,3-benzenedicarboxylic acid (NO(2)-H(2)BDC) and 1,2-bis(4-pyridyl)ethylene (dpe).