Synthesis of 1-alkynyl(diphenyl)onium salts of group 16 elements via heteroatom transfer reaction of 1-alkynyl(phenyl)-lambda 3-iodanes

Masahito Ochiai; Takema Nagaoka; Takuya Sueda; Jie Yan; Da-Wei Chen; Kazunori Miyamoto

doi:10.1039/b212512a

Synthesis of 1-alkynyl(diphenyl)onium salts of group 16 elements via heteroatom transfer reaction of 1-alkynyl(phenyl)-lambda 3-iodanes

Org Biomol Chem. 2003 May 7;1(9):1517-21. doi: 10.1039/b212512a.

Authors

Masahito Ochiai¹, Takema Nagaoka, Takuya Sueda, Jie Yan, Da-Wei Chen, Kazunori Miyamoto

Affiliation

¹ Faculty of Pharmaceutical Sciences, University of Tokushima, 1-78 Shomachi, Tokushima 770-8505, Japan. mochiai@ph2.tokushima-u.ac.jp

PMID: 12926281
DOI: 10.1039/b212512a

Abstract

1-Alkynyl(phenyl)-lambda 3-iodanes undergo selective transfer of the alkynyl groups over the phenyl group onto diphenyl chalcogens. Exposure of 1-alkynyl(phenyl)-lambda 3-iodanes to diphenyl chalcogens (S, Se, and Te) in dichloromethane or 1,2-dichloroethane affords 1-alkynyl(diphenyl)sulfonium, -selenonium, and -telluronium salts in high yields.