Thermally induced stoichiometric and catalytic O-atom transfer by a non-heme iron(III)-nitro complex: first example of reversible [Fe-NO]7<-->FeIII-NO2 transformation in the presence of dioxygen

Angew Chem Int Ed Engl. 2003 Sep 29;42(37):4517-21. doi: 10.1002/anie.200352070.
No abstract available

Publication types

  • Research Support, U.S. Gov't, Non-P.H.S.
  • Research Support, U.S. Gov't, P.H.S.

MeSH terms

  • Catalysis
  • Heme
  • Iron / chemistry*
  • Models, Chemical
  • Models, Molecular
  • Molecular Conformation
  • Nitrogen / chemistry*
  • Organophosphorus Compounds / chemistry
  • Oxygen / chemistry*
  • Temperature*

Substances

  • Organophosphorus Compounds
  • triphenylphosphine
  • Heme
  • Iron
  • Nitrogen
  • Oxygen