Stepwise evolution of the structure and electronic properties of DNA

J Am Chem Soc. 2003 Oct 22;125(42):12729-31. doi: 10.1021/ja036449k.

Abstract

The optical properties of a family of duplex DNA conjugates possessing from 1 to 11 A:T base pairs and covalently attached stilbene chromophores at both ends have been investigated. As few as from two to four base bairs are needed to establish base-pair absorption and circular dichroism spectra similar to those of longer oligomers. The stilbene chromophores exhibit exciton-coupled circular dichroism, which can be observed even with 11 intervening base pairs, a distance of ca. 40 A. The dependence of the sign and amplitude of these spectra reveals the ability of B-DNA to serve as a helical ruler.

Publication types

  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Circular Dichroism
  • DNA / chemistry*
  • Models, Molecular
  • Nucleic Acid Conformation
  • Oligonucleotides / chemistry
  • Poly A / chemistry
  • Poly T / chemistry
  • Spectrophotometry, Ultraviolet
  • Stilbenes / chemistry

Substances

  • Oligonucleotides
  • Stilbenes
  • Poly A
  • Poly T
  • poly A-T
  • DNA