Abstract
[reaction: see text] A highly efficient catalytic borylation process with aryldiazonium ions was developed using a carbene-palladium catalyst formed in situ to give arylpinacolatoborane products. An X-ray structure for the N-heterocyclic carbene-palladium complex, used as the catalyst formed from bis(2,6-diisopropylphenyl)-4,5-dihydroimidazolium chloride, was obtained without added base.
Publication types
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, P.H.S.
MeSH terms
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Boron / chemistry*
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Catalysis
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Crystallography, X-Ray
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Hydrocarbons
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Hydrogen-Ion Concentration
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Ions / chemistry
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Ligands
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Methane / analogs & derivatives*
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Methane / chemistry*
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Molecular Conformation
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Molecular Structure
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Palladium / chemistry*
Substances
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Hydrocarbons
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Ions
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Ligands
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carbene
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Palladium
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Boron
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Methane