Structural and functional characterization of myotoxin I, a Lys49 phospholipase A2 homologue from the venom of the snake Bothrops atrox

Toxicon. 2004 Jul;44(1):91-101. doi: 10.1016/j.toxicon.2004.04.013.

Abstract

A new myotoxin was isolated from the venom of Bothrops atrox from Colombia. B. atrox myotoxin I is a homodimer, with a subunit molecular mass of 13,826, and a pI of 8.9. Its complete nucleotide sequence was obtained by cDNA cloning, indicating a mature product of 122 residues that belongs to the family of Lys49 phospholipase A(2) (PLA(2)) homologues, a subgroup of catalytically inactive proteins within the group IIA. Accordingly, the toxin was devoid of phospholipase and anticoagulant activities, in vitro. In mice, it induced conspicuous local myonecrosis, edema, and a systemic interleukin-6 response. In vitro, it was cytolytic upon myoblasts, and weakly bactericidal. The toxin showed highest homology with other Lys49 PLA(2)s, both in its primary and three-dimensional modeled structure, although with an evident difference in the C-terminal region. Unlike Lys49 proteins of American crotalids having 121 residues, this toxin presents an insertion (Asn) between positions 118 and 119. Despite several substitutions within the C-terminal region 115-129 between B. atrox myotoxin I and B. asper myotoxin II, antibodies against synthetic peptide 115-129 of the latter were strongly cross-reactive to the former, indicating the antigenic conservation of this site, known to be critical for the membrane-damaging activities of Lys49 myotoxins.

Publication types

  • Comparative Study
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amino Acid Sequence
  • Animals
  • Antibodies / immunology
  • Base Sequence
  • Bothrops*
  • Cross Reactions / immunology
  • Crotalid Venoms / chemistry*
  • DNA, Complementary / genetics
  • Edema / chemically induced
  • Electrophoresis, Polyacrylamide Gel
  • Group II Phospholipases A2
  • Immunoenzyme Techniques
  • Interleukin-6 / metabolism
  • Mice
  • Molecular Sequence Data
  • Muscle, Skeletal / drug effects
  • Muscle, Skeletal / pathology
  • Myoblasts / drug effects
  • Necrosis
  • Neurotoxins / chemistry*
  • Neurotoxins / genetics*
  • Neurotoxins / toxicity
  • Phospholipases A / chemistry*
  • Phospholipases A / genetics*
  • Phospholipases A / toxicity
  • Phospholipases A2
  • Protein Conformation
  • Reptilian Proteins
  • Sequence Alignment
  • Sequence Analysis, DNA

Substances

  • Antibodies
  • Crotalid Venoms
  • DNA, Complementary
  • Interleukin-6
  • Neurotoxins
  • Reptilian Proteins
  • Phospholipases A
  • Group II Phospholipases A2
  • Phospholipases A2
  • myotoxin I