Homologous expression of the feruloyl esterase B gene from Aspergillus niger and characterization of the recombinant enzyme

Protein Expr Purif. 2004 Sep;37(1):126-33. doi: 10.1016/j.pep.2004.05.019.

Abstract

The faeB gene encoding the feruloyl esterase B (FAEB) was isolated from Aspergillus niger BRFM131 genomic DNA. The faeB gene, with additional sequence coding for a C-terminal histidine tag, was inserted into an expression vector under the control of the gpd promoter and trpC terminator and expressed in a protease deficient A. niger strain. Homologous overproduction allows to reach an esterase activity of 18 nkat mL(-1) against MCA as substrate. The improvement factor was 16-fold higher as compared to the production level obtained with non-transformed A. niger strain induced by sugar beet pulp. The corresponding secretion yield was estimated to be around 100 mg L(-1). Recombinant FAEB was purified 14.6-fold to homogeneity from an 8-day-old culture by a single affinity chromatographic step with a recovery of 64%. SDS-PAGE revealed a single band with a molecular mass of 75 kDa, while under non-denatured conditions, native enzyme has a molecular mass of around 150 kDa confirming that the recombinant FAEB is a homodimer. The recombinant and native FAEB have the same characteristics concerning temperature and pH optima, i.e., 50 degrees C and 6, respectively. In addition, the recombinant FAEB was determined to be quite stable up to 50 degrees C for 120 min. Kinetic constants for MCA, MpCA, and chlorogenic acid (5-O-caffeoyl quinic acid) were as follows: Km: 0.13, 0.029, and 0.16 mM and Vmax: 1101, 527.6, and 28.3 nkat mg(-1), respectively. This is the first report on the homologous overproduction of feruloyl esterase B in A. niger.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Aspergillus niger* / enzymology
  • Aspergillus niger* / genetics
  • Carboxylic Ester Hydrolases* / chemistry
  • Carboxylic Ester Hydrolases* / genetics
  • Carboxylic Ester Hydrolases* / isolation & purification
  • Carboxylic Ester Hydrolases* / metabolism
  • Cloning, Molecular
  • Enzyme Stability
  • Fungal Proteins* / chemistry
  • Fungal Proteins* / genetics
  • Fungal Proteins* / isolation & purification
  • Fungal Proteins* / metabolism
  • Hydrogen-Ion Concentration
  • Isoenzymes* / genetics
  • Isoenzymes* / metabolism
  • Recombinant Proteins* / chemistry
  • Recombinant Proteins* / genetics
  • Recombinant Proteins* / isolation & purification
  • Recombinant Proteins* / metabolism
  • Temperature

Substances

  • Fungal Proteins
  • Isoenzymes
  • Recombinant Proteins
  • Carboxylic Ester Hydrolases
  • feruloyl esterase