Novel polyaniline-supported molybdenum-catalyzed aerobic oxidation of alcohols to aldehydes and ketones

Org Lett. 2004 Dec 23;6(26):4821-4. doi: 10.1021/ol048195t.

Abstract

[reaction: see text] Oxidation of alcohols to aldehydes and ketones has been studied in high yields using molecular oxygen and a catalytic amount of 1 in toluene under stirring (ca. 100 degrees C). The reactions of primary alcohols are faster compared to secondary alcohols and the catalyst 1 can be recycled without loss of activity.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Alcohols / chemistry*
  • Aldehydes / chemical synthesis*
  • Aldehydes / chemistry
  • Aniline Compounds / chemistry*
  • Catalysis
  • Ketones / chemical synthesis*
  • Ketones / chemistry
  • Molecular Structure
  • Molybdenum / chemistry*
  • Organometallic Compounds / chemistry*
  • Oxidation-Reduction
  • Oxygen / chemistry
  • Stereoisomerism
  • Time Factors

Substances

  • Alcohols
  • Aldehydes
  • Aniline Compounds
  • Ketones
  • Organometallic Compounds
  • polyaniline
  • Molybdenum
  • Oxygen