3-Aryl beta-carbolin-1-ones as a new class of potent inhibitors of tumor cell proliferation: synthesis and biological evaluation

Org Biomol Chem. 2005 Mar 7;3(5):911-6. doi: 10.1039/b412921k. Epub 2005 Feb 7.

Abstract

A novel three-step synthesis of 3-aryl beta-carbolin-1-ones from non-indole starting materials has been developed. The two nitrogen atoms in beta-carbolin-1-one were introduced efficiently by Michael addition of ethyl acetamidocyanoacetate to chalcone. The desired pyridone and indole rings were assembled by an intramolecular ketone-nitrile annulation mediated by aqueous HCl-HOAc and a Cu(I)-catalyzed intramolecular N-arylation of the amide, respectively. The target compounds were found to possess significant activity against tumor cell proliferation.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Antineoplastic Agents / chemical synthesis*
  • Antineoplastic Agents / chemistry
  • Antineoplastic Agents / pharmacology
  • Carbolines / chemical synthesis*
  • Carbolines / chemistry
  • Carbolines / pharmacology
  • Cell Proliferation / drug effects*
  • Copper / chemistry
  • Crystallography, X-Ray
  • HeLa Cells
  • Humans
  • Inhibitory Concentration 50
  • Ketones / chemistry
  • Molecular Conformation
  • Molecular Structure
  • Nitriles / chemistry

Substances

  • Antineoplastic Agents
  • Carbolines
  • Ketones
  • Nitriles
  • cuprous ion
  • Copper