Nanowire dye-sensitized solar cells

Nat Mater. 2005 Jun;4(6):455-9. doi: 10.1038/nmat1387. Epub 2005 May 15.

Abstract

Excitonic solar cells-including organic, hybrid organic-inorganic and dye-sensitized cells (DSCs)-are promising devices for inexpensive, large-scale solar energy conversion. The DSC is currently the most efficient and stable excitonic photocell. Central to this device is a thick nanoparticle film that provides a large surface area for the adsorption of light-harvesting molecules. However, nanoparticle DSCs rely on trap-limited diffusion for electron transport, a slow mechanism that can limit device efficiency, especially at longer wavelengths. Here we introduce a version of the dye-sensitized cell in which the traditional nanoparticle film is replaced by a dense array of oriented, crystalline ZnO nanowires. The nanowire anode is synthesized by mild aqueous chemistry and features a surface area up to one-fifth as large as a nanoparticle cell. The direct electrical pathways provided by the nanowires ensure the rapid collection of carriers generated throughout the device, and a full Sun efficiency of 1.5% is demonstrated, limited primarily by the surface area of the nanowire array.

Publication types

  • Evaluation Study
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Coloring Agents / chemistry
  • Coloring Agents / radiation effects
  • Dose-Response Relationship, Radiation
  • Electric Power Supplies*
  • Electrochemistry / instrumentation*
  • Electrochemistry / methods
  • Equipment Design
  • Equipment Failure Analysis
  • Light
  • Materials Testing
  • Nanotechnology / instrumentation*
  • Nanotechnology / methods
  • Nanotubes / chemistry*
  • Nanotubes / radiation effects*
  • Nanotubes / ultrastructure
  • Radiation Dosage
  • Solar Energy
  • Titanium / chemistry*
  • Titanium / radiation effects
  • Zinc Oxide / chemistry*
  • Zinc Oxide / radiation effects

Substances

  • Coloring Agents
  • titanium dioxide
  • Titanium
  • Zinc Oxide