H2, N2, CO, and CO2 sorption properties of a series of robust sodalite-type microporous coordination polymers

Jorge A R Navarro; Elisa Barea; Juan M Salas; Norberto Masciocchi; Simona Galli; Angelo Sironi; Conchi O Ania; José B Parra

doi:10.1021/ic060049r

H2, N2, CO, and CO2 sorption properties of a series of robust sodalite-type microporous coordination polymers

Inorg Chem. 2006 Mar 20;45(6):2397-9. doi: 10.1021/ic060049r.

Authors

Jorge A R Navarro¹, Elisa Barea, Juan M Salas, Norberto Masciocchi, Simona Galli, Angelo Sironi, Conchi O Ania, José B Parra

Affiliation

¹ Departamento de Química Inorganica, Universidad de Granada, Av. Fuentenueva S/N, 18071 Granada, Spain. jarn@ugr.es

PMID: 16529456
DOI: 10.1021/ic060049r

Abstract

H2, N2, CO, and CO2 are readily incorporated in the porous, 3D sodalitic frameworks of coordination polymers of the [ML2]n type, with M = Pd(II) or Cu(II) and HL = 2-hydroxypyrimidine or 4-hydroxypyrimidine. The metal ion and ligand functionalization modulate their sorption properties, making these materials suitable for gas storage and separation purposes.