A highly reduced vanadium(III/IV) polyoxovanadate comprising an octavanadyl square-prism surrounding a dimetallic vanadium(III) fragment

Rebecca H Laye; Qiang Wei; Pamela V Mason; Maheswaran Shanmugam; Simon J Teat; Euan K Brechin; David Collison; Eric J L McInnes

doi:10.1021/ja062723+

A highly reduced vanadium(III/IV) polyoxovanadate comprising an octavanadyl square-prism surrounding a dimetallic vanadium(III) fragment

J Am Chem Soc. 2006 Jul 19;128(28):9020-1. doi: 10.1021/ja062723+.

Authors

Rebecca H Laye¹, Qiang Wei, Pamela V Mason, Maheswaran Shanmugam, Simon J Teat, Euan K Brechin, David Collison, Eric J L McInnes

Affiliation

¹ School of Chemistry, The University of Manchester, Manchester M13 9PL, UK, and CCLRC Daresbury Laboratory, Daresbury, Cheshire WA4 4AD, UK.

PMID: 16834360
DOI: 10.1021/ja062723+

Abstract

The synthesis, crystal structure and preliminary magnetic studies are reported for a very highly reduced, VIV8VIII2, polyoxo(alkoxo)vanadate with a unique square prismatic topology.