Electrokinetic energy conversion efficiency in nanofluidic channels

Nano Lett. 2006 Oct;6(10):2232-7. doi: 10.1021/nl061524l.

Abstract

We theoretically evaluate the prospect of using electrokinetic phenomena to convert hydrostatic energy to electrical power. An expression is derived for the energy conversion efficiency of a two-terminal fluidic device in terms of its linear electrokinetic response properties. For a slitlike nanochannel of constant surface charge density, we predict that the maximum energy conversion efficiency occurs at low salt concentrations. An analytic expression for the regime of strong double-layer overlap reveals that the efficiency depends only on the ratio of the channel height to the Gouy-Chapman length, and the product of the viscosity and the counterion mobility. We estimate that an electrokinetic energy conversion device could achieve a maximum efficiency of 12% for simple monovalent ions in aqueous solution.

Publication types

  • Evaluation Study
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Computer Simulation
  • Computer-Aided Design
  • Electric Power Supplies*
  • Electricity*
  • Energy Transfer*
  • Equipment Design
  • Equipment Failure Analysis
  • Kinetics
  • Microfluidics / instrumentation*
  • Microfluidics / methods
  • Models, Theoretical*
  • Nanotechnology / instrumentation*
  • Nanotechnology / methods
  • Transducers*