High formation of superoxide anion and nitric oxide, and matrix metalloproteinases activity in vascular wall of rectal carcinoma vessels

Exp Oncol. 2006 Dec;28(4):323-5.

Abstract

Aim: To study the relationship between the level of generation of reactive oxygen species (ROS) and nitric oxide (NO) and activity of matrix metalloproteinases (MMPs) MMP-2 and MMP-9 in the vessels isolated from rectal tumors and Arteria rectalis superior.

Methods: EPR at the room temperature and 77 degrees K, Spin Traps technology and zymography in polyacrylamide gels were applied.

Results: In the vessels isolated from rectal tumors and Arteria rectalis superior high levels of ROS, NO and formation of complexes of NO with FeS-proteins at the sites of electron-transporting chain of mitochondria have been detected. High activities of MMP-2 and MMP-9 in vascular wall were also observed. The direct positive correlation between the rate of NO generation and formation of complexes of NO with FeS-proteins as well as between ROS and NO formation and MMPs activities have been revealed.

Conclusion: Altered oxidative equilibrium in mitochondria of cells in vascular wall promotes formation of cell hypoxia and its autocatalytic potentiation accompanied with activation of MMPs.

MeSH terms

  • Electron Spin Resonance Spectroscopy
  • Endothelium, Vascular / metabolism*
  • Humans
  • Matrix Metalloproteinases / metabolism*
  • Mitochondria / metabolism
  • Nitric Oxide / biosynthesis*
  • Rectal Neoplasms / blood supply*
  • Rectal Neoplasms / metabolism*
  • Spin Trapping
  • Superoxides / metabolism*

Substances

  • Superoxides
  • Nitric Oxide
  • Matrix Metalloproteinases