A ketone oximate based cyclic cationic [Ni(II)4] inverse metallacrown from simultaneous chelation and bridging of two ligands

Dalton Trans. 2007 May 28:(20):1989-92. doi: 10.1039/b704678m. Epub 2007 Apr 13.

Abstract

The Ni(4) inverse metallacrown (NHEt(3)) [Ni(4)(bmo)4(Hael)2(ael)2](ClO(4))3 [(NHEt(3)).1.(ClO(4))3], with the inverse 12-MC-4 motif, has been assembled via simultaneous chelation and bridging of butan-2,3-dionemonoxime (Hbmo) and 2-amino ethanol (Hael).

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amino Alcohols / chemistry
  • Cations, Divalent
  • Chelating Agents / chemistry*
  • Epoxy Compounds / chemistry
  • Ethers, Cyclic / chemistry*
  • Ketones / chemistry*
  • Ligands
  • Molecular Structure
  • Nickel / chemistry*
  • Organometallic Compounds / chemistry*
  • Oximes / chemistry*
  • Temperature

Substances

  • Amino Alcohols
  • Cations, Divalent
  • Chelating Agents
  • Epoxy Compounds
  • Ethers, Cyclic
  • Ketones
  • Ligands
  • Organometallic Compounds
  • Oximes
  • diepoxybutane
  • Nickel