Cobalt-rhodium heterobimetallic nanoparticle-catalyzed synthesis of alpha,beta-unsaturated amides from internal alkynes, amines, and carbon monoxide

Ji Hoon Park; Sun Young Kim; Soo Min Kim; Young Keun Chung

doi:10.1021/ol0706760

Cobalt-rhodium heterobimetallic nanoparticle-catalyzed synthesis of alpha,beta-unsaturated amides from internal alkynes, amines, and carbon monoxide

Org Lett. 2007 Jun 21;9(13):2465-8. doi: 10.1021/ol0706760. Epub 2007 May 23.

Authors

Ji Hoon Park¹, Sun Young Kim, Soo Min Kim, Young Keun Chung

Affiliation

¹ Intelligent Textile System Research Center, Department of Chemistry, College of Natural Sciences, Seoul National University, Seoul 151-747, Korea.

PMID: 17518475
DOI: 10.1021/ol0706760

Abstract

The first example of cobalt-rhodium heterobimetallic nanoparticle-catalyzed synthesis of alkenyl amides from alkynes, amines, and carbon monoxide is described.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Alkynes / chemistry
Amides / chemical synthesis*
Amines / chemistry
Carbon Monoxide / chemistry
Catalysis
Cobalt / chemistry*
Metal Nanoparticles / chemistry*
Molecular Structure
Rhodium / chemistry*

Substances

Alkynes
Amides
Amines
Cobalt
Carbon Monoxide
Rhodium