Product deuterium isotope effect for orotidine 5'-monophosphate decarboxylase: evidence for the existence of a short-lived carbanion intermediate

J Am Chem Soc. 2007 Oct 31;129(43):12946-7. doi: 10.1021/ja076222f. Epub 2007 Oct 5.
No abstract available

Publication types

  • Research Support, N.I.H., Extramural

MeSH terms

  • Carbon / chemistry*
  • Deuterium
  • Magnetic Resonance Spectroscopy
  • Molecular Structure
  • Orotidine-5'-Phosphate Decarboxylase / chemistry*
  • Orotidine-5'-Phosphate Decarboxylase / metabolism*
  • Uridine Monophosphate / analogs & derivatives
  • Uridine Monophosphate / chemistry
  • Uridine Monophosphate / metabolism

Substances

  • orotidylic acid
  • Carbon
  • Deuterium
  • Uridine Monophosphate
  • Orotidine-5'-Phosphate Decarboxylase