Specific ion adsorption and short-range interactions at the air aqueous solution interface

Phys Rev Lett. 2007 Aug 24;99(8):086105. doi: 10.1103/PhysRevLett.99.086105. Epub 2007 Aug 24.

Abstract

We have investigated the surface composition of alkali-halide aqueous solutions using grazing incidence x-ray fluorescence. Using mixtures of salts as a means to enhance the short-range effects, small differences in concentration over a few angstrom could be resolved, with, for example I- or Br- > Cl-. In order to explain our data, we need to include an effective potential accounting for the short-range (A) solvent mediated couplings, responsible for specific effects together with dispersion forces. This attractive potential (few k{B}T for halides) leads to concentration profiles which are in good agreement with recent numerical simulations.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Adsorption
  • Salts
  • Solutions*
  • Water*
  • X-Rays

Substances

  • Salts
  • Solutions
  • Water