Abstract
Organoboranes react with phosphorus-containing carbenoids to produce a variety of functionalized organophosphorus compounds under mild conditions. In some cases, selective migration of one group attached to boron can be observed. Phosphonite-borane complexes are introduced as novel synthons for the synthesis of phosphinic esters.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, Non-U.S. Gov't
MeSH terms
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Boranes / chemistry*
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Esters
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Hydrocarbons / chemistry
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Methane / analogs & derivatives*
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Methane / chemistry
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Molecular Structure
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Organophosphorus Compounds / chemical synthesis*
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Organophosphorus Compounds / chemistry
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Phosphorus / chemistry*
Substances
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Boranes
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Esters
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Hydrocarbons
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Organophosphorus Compounds
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carbene
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Phosphorus
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Methane