Zn-catalyzed asymmetric allylation for the synthesis of optically active allylglycine derivatives. Regio- and stereoselective formal alpha-addition of allylboronates to hydrazono esters

J Am Chem Soc. 2008 Mar 12;130(10):2914-5. doi: 10.1021/ja710627x. Epub 2008 Feb 16.

Authors

Mari Fujita¹, Takashi Nagano, Uwe Schneider, Tomoaki Hamada, Chikako Ogawa, Shū Kobayashi

Affiliation

¹ Department of Chemistry, School of Science and Graduate School of Pharmaceutical Sciences, The University of Tokyo, The HFRE Division, ERATO, Japan Science Technology Agency, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.

PMID: 18278917
DOI: 10.1021/ja710627x

No abstract available

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Alkylation
Allylglycine / analogs & derivatives*
Allylglycine / chemical synthesis*
Allylglycine / chemistry
Boronic Acids / chemistry*
Catalysis
Esters / chemistry*
Molecular Structure
Optics and Photonics*
Stereoisomerism
Zinc / chemistry*

Substances

Boronic Acids
Esters
Allylglycine
Zinc