Optimization of UDP-N-acetylmuramic acid synthesis

Pharmazie. 2008 Feb;63(2):102-6.

Abstract

UDP-N-acetylmuramic acid (UDP-MurNAc) is a substrate of MurC, an important enzyme in the intracellular pathway of bacterial peptidoglycan biosynthesis. Various approaches towards preparation of UDP-MurNAc have been published but these synthetic preparations were shown to include many problematic steps. An optimization study with the focus on muramyl phosphate and UMP-morpholidate coupling was performed, resulting in a synthetic procedure enabling robust and easily reproducible production on a multi-gram scale.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Chemical Phenomena
  • Chemistry
  • Chromatography, High Pressure Liquid
  • Indicators and Reagents
  • Magnetic Resonance Spectroscopy
  • Phosphorylation
  • Uridine Diphosphate N-Acetylmuramic Acid / chemical synthesis*

Substances

  • Indicators and Reagents
  • Uridine Diphosphate N-Acetylmuramic Acid