Abstract
Two remote dialkylaluminium centres supported by a macrocyclic Schiff base ligand exhibited beneficial cooperative effects, whilst aluminoxane-type bonding proved to be detrimental to activity for the ring opening polymerisation of epsilon-caprolactone.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Aluminum / chemistry*
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Caproates / chemistry*
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Catalysis
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Crystallography, X-Ray
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Lactones / chemistry*
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Ligands
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Macrocyclic Compounds / chemical synthesis
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Macrocyclic Compounds / chemistry*
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Models, Molecular
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Molecular Conformation
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Organometallic Compounds / chemical synthesis
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Organometallic Compounds / chemistry*
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Polymers / chemical synthesis*
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Polymers / chemistry
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Schiff Bases / chemistry*
Substances
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Caproates
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Lactones
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Ligands
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Macrocyclic Compounds
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Organometallic Compounds
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Polymers
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Schiff Bases
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caprolactone
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Aluminum