Unprecedented coexistence of cyano-bridged Mn4(III)Cr(III) and Mn2(III)Cr(III) heterobimetallic complexes in one single crystal

Diana Visinescu; Luminita Marilena Toma; Francesc Lloret; Oscar Fabelo; Catalina Ruiz-Pérez; Miguel Julve

doi:10.1039/b816412f

Unprecedented coexistence of cyano-bridged Mn4(III)Cr(III) and Mn2(III)Cr(III) heterobimetallic complexes in one single crystal

Dalton Trans. 2009 Jan 7:(1):37-40. doi: 10.1039/b816412f. Epub 2008 Nov 17.

Authors

Diana Visinescu¹, Luminita Marilena Toma, Francesc Lloret, Oscar Fabelo, Catalina Ruiz-Pérez, Miguel Julve

Affiliation

¹ Departament de Química Inorgànica/Instituto de Ciencia Molecular (ICMol), Universitat de València, Edificio de Institutos s/n, Paterna 46980, València, Spain.

PMID: 19081969
DOI: 10.1039/b816412f

Abstract

The penta-[{MnIII(4-MeO-salen)(H2O)(micro-CN)}4CrIII(CN)2]+ and trinuclear [{MnIII(4-MeO-salen)(H2O)(micro-CN)}2CrIII(CN)4](-) units coexist in 1 with weak antiferromagnetic interactions which are overcome by a dc magnetic field of 2.5 T.