Abstract
The synthesis and characterization of a biradical containing a 1,3-bisdiphenylene-2-phenylallyl (BDPA) free radical covalently attached to a 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) free radical are described. The synthesis of the biradical is a step toward improved polarizing agents for dynamic nuclear polarization (DNP).
Publication types
-
Research Support, N.I.H., Extramural
-
Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
-
Allyl Compounds / chemical synthesis*
-
Allyl Compounds / chemistry
-
Crystallography, X-Ray
-
Cyclic N-Oxides / chemical synthesis*
-
Cyclic N-Oxides / chemistry*
-
Electron Spin Resonance Spectroscopy
-
Models, Molecular
-
Molecular Conformation
-
Molecular Structure
Substances
-
Allyl Compounds
-
BDPA-TEMPO biradical
-
Cyclic N-Oxides
-
bis-diphenylene-phenyl-allyl
-
TEMPO