Synthesis and spectroscopic studies on azo-dye derivatives of polymetallic lanthanide complexes: using diazotization to link metal complexes together

Matteo P Placidi; Aaron Joseph L Villaraza; Louise S Natrajan; Daniel Sykes; Alan M Kenwright; Stephen Faulkner

doi:10.1021/ja904362f

Synthesis and spectroscopic studies on azo-dye derivatives of polymetallic lanthanide complexes: using diazotization to link metal complexes together

J Am Chem Soc. 2009 Jul 29;131(29):9916-7. doi: 10.1021/ja904362f.

Authors

Matteo P Placidi¹, Aaron Joseph L Villaraza, Louise S Natrajan, Daniel Sykes, Alan M Kenwright, Stephen Faulkner

Affiliation

¹ School of Chemistry, University of Manchester, Oxford Road, Manchester M13 9PL, UK.

PMID: 19580269
DOI: 10.1021/ja904362f

Abstract

Heteronuclear tetrametallic lanthanide complexes have been synthesized from stable complexes by diazotization and azo-compound formation. Luminescence spectroscopy has been used to show that the complexes used as building blocks are stable under the reaction conditions.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Azo Compounds / chemistry*
Coloring Agents / chemical synthesis*
Coloring Agents / chemistry*
Kinetics
Lanthanoid Series Elements / chemistry*
Magnetic Resonance Spectroscopy / methods
Molecular Structure
Organometallic Compounds / chemical synthesis*
Organometallic Compounds / chemistry*
Spectroscopy, Near-Infrared / methods

Substances

Azo Compounds
Coloring Agents
Lanthanoid Series Elements
Organometallic Compounds