Abstract
Functionalized (Z,E)-1-halo-1,3-dienol esters are synthesized in a highly stereoselective manner via CrCl2-mediated rearrangement of allylic trihalomethylcarbinol esters induced by microwave irradiation.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, Non-U.S. Gov't
MeSH terms
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Chlorides / chemistry*
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Chromium Compounds / chemistry*
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Esters / chemical synthesis*
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Esters / chemistry
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Methane / analogs & derivatives*
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Methane / chemistry
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Microwaves*
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Molecular Structure
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Stereoisomerism
Substances
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Chlorides
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Chromium Compounds
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Esters
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carbene
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chromous chloride
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Methane