Continuous lipase-catalyzed production of fatty acid ethyl esters from soybean oil in compressed fluids

Bioresour Technol. 2009 Dec;100(23):5818-26. doi: 10.1016/j.biortech.2009.06.081. Epub 2009 Jul 18.

Abstract

This work investigates the continuous production of fatty acid ethyl esters from soybean oil in compressed fluids, namely carbon dioxide, propane and n-butane, using immobilized Novozym 435 as catalyst. The experiments were performed in a packed-bed bioreactor evaluating the effects of temperature in the range of 30-70 degrees C, from 50 to 150 bar, oil to ethanol molar ratio of 1:6-1:18 and solvent to substrates mass ratio of 4:1-10:1. In contrast to the use of carbon dioxide and n-butane, results showed that lipase-catalyzed alcoholysis in a continuous tubular reactor in compressed propane might be a potential route to biodiesel production as high reaction conversions were achieved at mild temperature (70 degrees C) and pressure (60 bar) conditions in short reaction times.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Bioelectric Energy Sources
  • Biotechnology / methods
  • Butanes / chemistry
  • Candida / enzymology
  • Carbon Dioxide / chemistry
  • Catalysis
  • Enzymes, Immobilized / chemistry
  • Esters / chemistry
  • Fungal Proteins
  • Glycine max / metabolism*
  • Lipase / chemistry*
  • Plant Oils / chemistry*
  • Pressure
  • Propane / chemistry
  • Temperature

Substances

  • Butanes
  • Enzymes, Immobilized
  • Esters
  • Fungal Proteins
  • Plant Oils
  • Carbon Dioxide
  • butane
  • Novozyme 435
  • Lipase
  • Propane