Abstract
Palladium poprocks: Hold on to your CO2! Enantioselective Pd-catalyzed decarboxylative alkylation of ketone enolates proceeds via η1-σ-allyl Pd-carboxylate complexes by slow loss of CO2.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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Alkylation
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Carboxylic Acids / chemistry*
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Catalysis
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Crystallography, X-Ray
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Ketones / chemistry*
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Molecular Conformation
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Palladium / chemistry*
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Stereoisomerism
Substances
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Carboxylic Acids
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Ketones
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Palladium