Abstract
A method for the oxidative alkylation of ketones through intramolecular allyl-group transfer within preformed allyldimethylsilyl enol ethers is reported. A number of examples are detailed, including a study into the effects of resident sterocenters within cyclic enol ethers.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, Non-U.S. Gov't
MeSH terms
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Alkylation
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Catalysis
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Combinatorial Chemistry Techniques
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Ethers / chemistry*
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Ketones / chemical synthesis*
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Ketones / chemistry
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Molecular Structure
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Organosilicon Compounds / chemistry*
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Oxidation-Reduction
Substances
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Ethers
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Ketones
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Organosilicon Compounds