Chiral Kagome network from thiacalix[4]arene tetrasulfonate at the interface of aqueous solution/Au(111) surface: an in situ electrochemical scanning tunneling microscopy study

J Am Chem Soc. 2010 Apr 28;132(16):5598-9. doi: 10.1021/ja101598p.

Abstract

A chiral Kagome network was fabricated at an aqueous solution/Au(111) interface by using a complicated stereo supramolecule thiacalix[4]arene tetrasulfonate as a building block. It opens the possibility to construct a 2D nanoporous network by various functional supramolecules and shows potential application in host-guest chemistry as well as chiral resolution.