Double conical crystal x-ray spectrometer for high resolution ultrafast x-ray absorption near-edge spectroscopy of Al K edge

Rev Sci Instrum. 2010 Jun;81(6):063107. doi: 10.1063/1.3441983.

Abstract

An x-ray spectrometer devoted to dynamical studies of transient systems using the x-ray absorption fine spectroscopy technique is presented in this article. Using an ultrafast laser-induced x-ray source, this optical device based on a set of two potassium acid phthalate conical crystals allows the extraction of x-ray absorption near-edge spectroscopy structures following the Al absorption K edge. The proposed experimental protocol leads to a measurement of the absorption spectra free from any crystal reflectivity defaults and shot-to-shot x-ray spectral fluctuation. According to the detailed analysis of the experimental results, a spectral resolution of 0.7 eV rms and relative fluctuation lower than 1% rms are achieved, demonstrated to be limited by the statistics of photon counting on the x-ray detector.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Absorption
  • Algorithms
  • Aluminum Compounds / chemistry
  • Equipment Design
  • Feasibility Studies
  • Lasers
  • Linear Models
  • Photons
  • Phthalic Acids
  • Potassium Compounds
  • Signal Processing, Computer-Assisted
  • Time Factors
  • X-Ray Absorption Spectroscopy / instrumentation*
  • X-Ray Absorption Spectroscopy / methods*

Substances

  • Aluminum Compounds
  • Phthalic Acids
  • Potassium Compounds
  • phthalic acid