We report results of laser desorption from water ice surfaces using XUV pulses from the free-electron laser in Hamburg (FLASH). This XUV to soft x-ray FEL provides femtosecond pulses at 20-200 eV photon energy with pulse energies up to 100 µJ. The interaction of this intense soft x-ray radiation with ice (H2O, D2O) adsorbed on highly oriented pyrolytic graphite (HOPG) yields the desorption of various ions, particularly H (+) (D (+) ), O (+) , O2 (+) and others. For H (+) and O (+) ions linear desorption yields are observed, while for O2 (+) a highly nonlinear desorption yield with n = (2.5 ± 0.2) is found. Kinetic energies of 1.8 eV, 559 meV and 390 meV for H (+) , O (+) , and O2 (+) , respectively, account for only a small part of the available excess energy.