μ-14,29-Di-tert-butyl-3,10,18,25-tetra-azatpenta-cyclo-[25.3.1.1.0.0]dotriaconta-1(31),4,6,8,12(32),14,16,19,21,23,27,29-dodeca-ene-31,32-diol-ato]bis-[(nitrato-κO,O')zinc(II)

Li-Jing Fan; Jian-Fang Ma; Bo Liu

doi:10.1107/S1600536809028530

μ-14,29-Di-tert-butyl-3,10,18,25-tetra-azatpenta-cyclo-[25.3.1.1.0.0]dotriaconta-1(31),4,6,8,12(32),14,16,19,21,23,27,29-dodeca-ene-31,32-diol-ato]bis-[(nitrato-κO,O')zinc(II)

Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 25;65(Pt 8):m985. doi: 10.1107/S1600536809028530.

Authors

Li-Jing Fan¹, Jian-Fang Ma, Bo Liu

Affiliation

¹ Department of Chemistry, Northeast Normal University, Changchun 130024, People's Republic of China.

Abstract

In the title centrosymmetric dinuclear zinc(II) complex, [Zn(2)(C(36)H(42)N(4)O(2))(NO(3))(2)], the Zn(II) atom has a distorted octa-hedral geometry, defined by two N atoms and two O atoms from the macrocyclic ligand and two O atoms from a chelating nitrate anion and are bridged by two phenolate O atoms, forming a four-membered Zn(2)O(2) ring.