HSP70 inhibition by the small-molecule 2-phenylethynesulfonamide impairs protein clearance pathways in tumor cells

Mol Cancer Res. 2011 Jul;9(7):936-47. doi: 10.1158/1541-7786.MCR-11-0019. Epub 2011 Jun 2.

Abstract

The evolutionarily conserved stress-inducible HSP70 molecular chaperone plays a central role in maintaining protein quality control in response to various forms of stress. Constitutively elevated HSP70 expression is a characteristic of many tumor cells and contributes to their survival. We recently identified the small-molecule 2-phenylethyenesulfonamide (PES) as a novel HSP70 inhibitor. Here, we present evidence that PES-mediated inhibition of HSP70 family proteins in tumor cells results in an impairment of the two major protein degradation systems, namely, the autophagy-lysosome system and the proteasome pathway. HSP70 family proteins work closely with the HSP90 molecular chaperone to maintain the stability and activities of their many client proteins, and PES causes a disruption in the HSP70/HSP90 chaperone system. As a consequence, many cellular proteins, including known HSP70/HSP90 substrates, accumulate in detergent-insoluble cell fractions, indicative of aggregation and functional inactivation. Overall, PES simultaneously disrupts several cancer critical survival pathways, supporting the idea of targeting HSP70 as a potential approach for cancer therapeutics.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Autophagy / drug effects*
  • Benzoquinones / pharmacology
  • Cell Line, Tumor
  • Female
  • Gene Expression Regulation, Neoplastic
  • HSP70 Heat-Shock Proteins / antagonists & inhibitors*
  • HSP70 Heat-Shock Proteins / metabolism
  • Humans
  • Lactams, Macrocyclic / pharmacology
  • Lysosomes / metabolism
  • Mice
  • Mice, Nude
  • Neoplasm Proteins / metabolism
  • Neoplasms / drug therapy*
  • Neoplasms / metabolism
  • Proteasome Endopeptidase Complex / metabolism
  • Sulfonamides / pharmacology*
  • Sulfonamides / therapeutic use
  • Xenograft Model Antitumor Assays

Substances

  • 2-phenylethylenesulfonamide
  • Benzoquinones
  • HSP70 Heat-Shock Proteins
  • Lactams, Macrocyclic
  • Neoplasm Proteins
  • Sulfonamides
  • tanespimycin
  • Proteasome Endopeptidase Complex