Enzyme-like control of carbocation deprotonation regioselectivity in supramolecular catalysis of the Nazarov cyclization

Angew Chem Int Ed Engl. 2011 Nov 4;50(45):10570-3. doi: 10.1002/anie.201105325. Epub 2011 Sep 20.

Authors

Courtney J Hastings¹, Mikael P Backlund, Robert G Bergman, Kenneth N Raymond

Affiliation

¹ Department of Chemistry, University of California, Berkeley, Berkeley, CA 94720-1416, USA.

PMID: 21932275
DOI: 10.1002/anie.201105325

No abstract available

Publication types

Research Support, Non-U.S. Gov't
Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

Catalysis
Cyclization
Cyclopentanes / chemistry*
Enzymes / chemistry*
Enzymes / metabolism*
Models, Molecular
Protons
Stereoisomerism

Substances

Cyclopentanes
Enzymes
Protons