Abstract
A gram-scale enantiospecific synthesis of the A'B'-subunit of angelmicin B is reported. The synthesis involves a Lewis acid catalyzed contrasteric Diels-Alder reaction and a tandem silyl zincate 1,6-addition/enolate oxidation sequence.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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Actinobacteria / chemistry
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Anthraquinones / chemical synthesis*
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Anthraquinones / chemistry
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Catalysis
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Lewis Acids / chemistry
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Molecular Structure
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Organosilicon Compounds / chemistry
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Oxidation-Reduction
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Stereoisomerism
Substances
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Anthraquinones
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Lewis Acids
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Organosilicon Compounds
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angelmicin B