Stimulation of Ca2+ uptake into epididymal bull spermatozoa by analogues of amiloride

Eur J Biochem. 1990 Sep 11;192(2):529-35. doi: 10.1111/j.1432-1033.1990.tb19257.x.

Abstract

Certain amiloride analogues 3',4'-dichlorobenzamil 2',4'-dimethylbenzamil and alpha',2'-benzobenzamil hydrochloride (ATBB) stimulate calcium accumulation and motility by epididymal bovine spermatozoa. This stimulation can be seen at a range of 0.1-0.4 mM, while at higher concentration there is inhibition of calcium uptake by these amiloride analogues. The amiloride derivative 5-(4-chlorobenzyl)-2',4'-dimethylbenzamil (CBDMB), which bears a 4-chlorobenzyl substituent on the 5-amino nitrogen atom, did not stimulate calcium uptake. The amiloride analogue 3',4'-dichlorobenzamil inhibits the Na+/Ca2(+)-exchange activity in isolated plasma membrane vesicles, and the stimulatory effect of 3',4'-dichlorobenzamil on calcium uptake into epididymal sperm could be seen in Na(+)-free medium. Thus, the stimulation of Ca2+ accumulation in the cells caused by 3',4'-dichlorobenzamil is not a result of inhibiting the Na(+)-dependent Ca2+ clearance. There is no stimulation of Ca2+ uptake into ejaculated cells by adding 3',4'-dichlorobenzamil, which is not due to the presence of the calcium-transport inhibitor (caltrin) in these cells [Rufo, G.A., Schoff, P.K. & Lardy, H.A. (1984) J. Biol. Chem. 259, 2547-2552]. The stimulatory effect of 3',4'-dichlorobenzamil on Ca2+ uptake is inhibited by the voltage-dependent Ca2(+)-channel blockers nifedipin and diltiazem. This indicates that the stimulation of Ca2+ uptake by the amiloride analogues is due to the activation of a voltage-dependent Ca2+ channel of the plasma membrane.

MeSH terms

  • Amiloride / analogs & derivatives*
  • Amiloride / pharmacology*
  • Animals
  • Calcium / metabolism*
  • Cattle
  • Cell Membrane / metabolism
  • Diltiazem / pharmacology
  • Epididymis
  • Filipin / pharmacology
  • Kinetics
  • Male
  • Nifedipine / pharmacology
  • Sodium / metabolism
  • Spermatozoa / drug effects
  • Spermatozoa / metabolism*
  • Structure-Activity Relationship

Substances

  • 3',4'-dichlorobenzamil
  • alpha',2'-benzobenzamil
  • 2',4'-dimethylbenzamil
  • Amiloride
  • Filipin
  • Sodium
  • Diltiazem
  • Nifedipine
  • Calcium