Plastic-syringe induced silicone contamination in organic photovoltaic fabrication: implications for small-volume additives

ACS Appl Mater Interfaces. 2012 Jun 27;4(6):2831-5. doi: 10.1021/am3001677. Epub 2012 May 21.

Abstract

Herein, the implications of silicone contamination found in solution-processed conjugated polymer solar cells are explored. Similar to a previous work based on molecular cells, we find this contamination as a result of the use of plastic syringes during fabrication. However, in contrast to the molecular case, we find that glass-syringe fabricated devices give superior performance than plastic-syringe fabricated devices in poly(3-hexylthiophene)-based cells. We find that the unintentional silicone addition alters the solution's wettability, which translates to a thinner, less absorbent film on spinning. With many groups studying the effects of small-volume additives, this work should be closely considered as many of these additives may also directly alter the solutions' wettability, or the amount of silicone dissolved off the plastic syringes, or both. Thereby, film thickness, which generally is not reported in detail, can vary significantly from device to device.

Publication types

  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Glass / chemistry
  • Plastics / chemistry*
  • Polystyrenes / chemistry
  • Silicones / chemistry*
  • Solar Energy*
  • Thiophenes / chemistry*
  • Tin Compounds / chemistry

Substances

  • Plastics
  • Polystyrenes
  • Silicones
  • Thiophenes
  • Tin Compounds
  • poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate)
  • poly(3-hexylthiophene)
  • indium tin oxide