Biofunctionalized quantum dots for live monitoring of stem cells: applications in regenerative medicine

Regen Med. 2012 May;7(3):335-47. doi: 10.2217/rme.12.21.

Abstract

Aim: This study aimed to live monitor the degree of endothelial progenitor cell (EPC) integration onto tissue-engineering scaffolds by conjugating relevant antibodies to quantum dots (QDs).

Materials & methods: Biocompatible mercaptosuccinic acid-coated QDs were functionalized with two different antibodies to EPC (CD133 with QDs of 640 nm wavelength [λ] and later-stage mature EPCs; and von Willebrand factor with QDs of λ595 and λ555 nm) using conventional carbomide and N-hydroxysuccinimide chemistry. Biofunctionalization was characterized with Fourier-transform infrared spectroscopy. Cell viability assays and gross morphology observations confirmed cytocompatibility and normal patterns of celluar growth. The antigens corresponding to each state of cell maturation were determined using a single excitation at λ488 nm.

Results: The optimal concentrations of antibody-QD conjugates were biocompatible, hemocompatible and determined the state of EPC transformation to endothelial cells.

Conclusion: Antibody-functionalized QDs suggest new applications in tissue engineering of polymer-based implants where cell integration can potentially be monitored without requiring the sacrifice of implants.

MeSH terms

  • AC133 Antigen
  • Antibodies / immunology
  • Antigens, CD / metabolism
  • Biocompatible Materials / chemistry
  • Biocompatible Materials / pharmacology*
  • Cell Shape / drug effects
  • Cell Survival / drug effects
  • Coronary Artery Bypass
  • Endothelial Cells / cytology*
  • Endothelial Cells / drug effects*
  • Endothelial Cells / metabolism
  • Fluorescence
  • Glycoproteins / metabolism
  • Hemolysis / drug effects
  • Humans
  • Materials Testing
  • Microscopy, Confocal
  • Peptides / metabolism
  • Quantum Dots*
  • Regenerative Medicine / methods*
  • Spectroscopy, Fourier Transform Infrared
  • Staining and Labeling
  • Stem Cells / cytology*
  • Stem Cells / drug effects*
  • Stem Cells / metabolism
  • Thiomalates / chemistry
  • Thiomalates / pharmacology
  • Tissue Engineering

Substances

  • AC133 Antigen
  • Antibodies
  • Antigens, CD
  • Biocompatible Materials
  • Glycoproteins
  • PROM1 protein, human
  • Peptides
  • Thiomalates
  • 2-thiomalic acid