Studies of atomic diffusion in Ni-Pt solid solution by x-ray photon correlation spectroscopy

J Phys Condens Matter. 2013 Feb 13;25(6):065401. doi: 10.1088/0953-8984/25/6/065401. Epub 2013 Jan 11.

Abstract

Atomic scale x-ray photon correlation spectroscopy (aXPCS) was used to study atomic diffusion in the Ni(97)Pt(3) solid solution with both a single crystal and a polycrystalline sample. Different jump diffusion models are discussed using experimental results and Monte Carlo simulations. The sensitivity of aXPCS experiments to short-range order (in this case governed by a strong Pt-Pt repulsive force) is demonstrated. The activation energy of 2.93(10) eV as well as diffusivities in the range of 10(-23) m(2) s(-1) at 830 K agree very well with the results of tracer diffusion studies at much higher temperatures.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Diffusion
  • Models, Theoretical*
  • Monte Carlo Method*
  • Nickel / chemistry*
  • Photoelectron Spectroscopy*
  • Photons*
  • Platinum / chemistry*
  • Solutions
  • X-Rays

Substances

  • Solutions
  • Platinum
  • Nickel